Sunday 12 May 2013
| Rayo Vallecano | v | Valencia | Estadio Teresa Rivero | 12:00 | |
| Real Betis | v | Celta Vigo | Estadio Benito Villamarin | 17:00 | |
| Atletico Madrid | v | Barcelona | Vicente Calderon | 19:00 | |
| Malaga | v | Sevilla | La Rosaleda | 21:00 |
| Monday 13 May 2013 |
| Real Sociedad | v | Granada | Anoeta | 22:00 |
| Saturday 18 May 2013 |
| Getafe | v | Valencia | Coliseum Alfonso Perez | 18:00 | |
| Granada | v | Osasuna | Los Carmenes | 20:00 | |
| Sevilla | v | Real Sociedad | Estadio Ramon Sanchez Pizjuan | 22:00 |
| Sunday 19 May 2013 |
| Levante | v | Rayo Vallecano | Ciutat de Valencia | 12:00 | |
| Deportivo La Coruna | v | Espanyol | Riazor | 17:00 | |
| Real Zaragoza | v | Athletic Bilbao | La Romareda | 19:00 | |
| Barcelona | v | Valladolid | Camp Nou | 21:00 |
| Monday 20 May 2013 |
| Mallorca | v | Real Betis | ONO Estadi | 22:00 |
| Wednesday 29 May 2013 |
| Atletico Madrid | v | Mallorca | Vicente Calderon | 21:00 | |
| Espanyol | v | Barcelona | Estadi Cornella-El Prat | 21:00 | |
| Real Sociedad | v | Real Madrid | Anoeta | 21:00 | |
| Athletic Bilbao | v | Levante | San Mames | 21:00 | |
| Real Betis | v | Real Zaragoza | Estadio Benito Villamarin | 21:00 | |
| Valencia | v | Granada | Mestalla | 21:00 | |
| Valladolid | v | Celta Vigo | Nuevo Jose Zorilla Stadium | 21:00 | |
| Osasuna | v | Sevilla | Reyno de Navarra | 21:00 | |
| Malaga | v | Deportivo La Coruna | La Rosaleda | 21:00 | |
| Getafe | v | Rayo Vallecano | Coliseum Alfonso Perez | 21:00 |
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